- Kosei Kirisawa, Shusuke Sato, Atsushi Minami, Hayato Maeda, Kazuaki Tanaka,
Masaru Hashimoto
Isolation and Identification of Xanthone, Benzofuran, and Spirolactone
Derivatives from Dinemasporium parastrigosum KT4144 and Their Plausible
Biosynthetic Pathways
J. Nat. Prod. in press.

- Azuma Murakami, Ryuhi Kanehara, Kazuaki Tanaka, and Masaru Hashimoto
Gregarithecinol, a Trichodiene/Bazzanene Derivative from Gregarithecium
curvisporum KT4079: DFT-Supported Stereochemical Elucidation of Units Linked
by a Rotatable Bond
Tetrahedron Letters, 2025, 88., (4), 1085-1090.

- Rui Kanehira, Hideki Abe, Hisanaka Ito, Ryuhi Kanehara Mr., Hayato Maeda, Kazuaki Tanaka, Masaru Hashimoto
Isolation of 6,7-Iso-felinone A: A Configurational Reinvestigation of Related Fungal Metabolites
J. Nat. Prod. 2025, 88 (4), 1085-1090.

- Ryuhi Kanehara, Yuki Oinuma, Hayato Maeda, Kazuaki Tanaka, Masaru Hashimoto
Triantaspirols A–C and Paraphaeolactone Cs from Paraphaeosphaeria sp. KT4192:
Sensitivity of CP3 in Distinguishing Close NMR Signals
J. Nat. Prod. 2024,87 (10),2487-2498.

- 橋本勝,: 天然物の不思議な構造に魅せられて, 有機合成化学協会誌, 2024, 82, 9, 922-925.
- 橋本勝: 計算機化学を利用した有機化合物の構造決定 密度汎関数化学シフト計算の進展, 月刊化学, 2024, 79, 9, 70-71.
- Taichiro Tokizaki, Ryuhi Kanehara, Hayato Maeda, Kazuaki Tanaka, and Masaru
Hashimoto
Highly Functionalized Spirobisnaphthalenes from Roussoella sp. KT4147
J. Nat. Prod. 2024, 87, 1798-1807.
- Shunta Kobayashi, Nurcahyo Iman Prakoso, Xin Zheng, Shin-ichiro Noro, Masaru
Hashimoto, Tatsuya Morozumi, and Taiki Umezawa
Synthesis and Conformational Analysis of α,β-Dichlorocarbonyl Compounds
Eur. J. Org. Chem., 2024, 27, e202400489..
- H. Arita, R. Tanaka, S. Kikukawa, T. Tomizawa, H. Sakata, M. Funada, K.
Tomiyama, M. Hashimoto, T. Tasaka, H. Tabata, K. Nakamura, K. Makino, T.
Oshitari, H. Natsugari, H. Takahashi: J. Med. Chem. 2024, 67, 10447-10463.l.
Fentanyl-Type Antagonist of the μ-Opioid Receptor: Important Role of Axial
Chirality in the Active Conformation
J. Med. Chem. 2024, 67, 10447-10463.
- K. Hashimoto, H. Maeda, M. Hashimoto,
Stereoselective Preparation of the Tricyclic Hexa-substituted Spirocyclopropane Core of Cyclohelminthol X
Org. Lett. 2024, 26, 5873-5876.

- Y. Horie, M. Uchikata, S. Ueda, G. Yamahira, M. Hashimoto, K. Sakamoto,
H. Ito, S. Hamada
In vitro synthesis of oryzamutaic acid H using recombinant L-lysineε-dehydrogenase
from Agrobacterium tumefaciens
J. Biotech. 2024, 385 , 42-48.
- Y. Oinuma, R. Kanehara, H. Maeda, T. Nishikawa, K. Konno, K. Tanaka, M Hashimoto
Isolation of Paraphaeoketones: A Plausible Biosynthetic Explanation for
Paraphaeolactones via a Benzilic Acid Rearrangement Rather than a Favorskii
Rearrangement
J. Nat. Prod. 2024, 87 (4), 1159-1170.

- K. Ujiie, C. Tanaka, M. Arai, M. Hashimoto, Y. Yoshida, T. Kawano, S. Tamura
Proposal for Structure Revision of Pinofuranoxin A through Total Syntheses of Stereoisomers
J. Nat.l Med, 2024, 78, 608-617.
- J. Wu, K. Uchida, A. Yoshikawa, M. Hashimoto, M. Kondo, K. Nihei, M. Ishii, J-H. Choi, Y. Miwa, C. Shoda, D. Lee, A. Nakai, T. Kurihara, C. N. D’Alessandro-Gabazza, M. Toda, T. Yasuma, E. C. Gabazza, H. Hirai, H. Kawagishi
"Fruiting Liquid” of Mushroom-Forming Fungi, A Novel Source of Bioactive Compounds – Fruiting-Body Inducer and HIF and Axl Inhibitors
J. Agr. Food Chem, 2023, 71, 13338-13345
- K. Hashimoto, K. Kimura, K. Ishida, E. Morita, K. Tanaka. M. Hashimoto
HIV-1 Integrase Inhibitor, Dihydroobionin B, and the Investigation of Its
Extraordinary Specific Rotation
J. Nat. Prod. 2023, 2139–2144

- R. Kanehara, Y. Oinuma, H. Maeda, M. Okazaki, K. Konno, K. Tanaka, M. Hashimoto
Pseudo-Enantiomeric Paraphaeolactones and Their Biosynthetic Derivatives
from Paraphaeosphaeria sp. KT4192: A Proposition of a Favorskii Rearrangement for Their Biosynthesis
J. Nat. Prod. 2023, 86, 1832-1843.

- J. Wu, Y. Kamiishi, K. Shimozaki, M. Kondo, M. Hashimoto, J. Choi, C. N
D’Alessandro-Gabazza, M. Toda, T. Yasuma, E. C Gabazza, H. Hirai, H. Kawagishi
Novel cyclopropyl compounds, cyclopropylvirgines A to G, from the fruiting
bodies of Amanita virgineoides
Bull. Chem. Soc. Jpn. 2023, 96 (6), 503-509
- R. Kanehara, K. Tanaka, T. Yamada, H. Koshino and M. Hashimoto
Termination of the Chirality Confusion of Peribysins
Bull. Chem. Soc. Jpn. 2023, 96 (4), 318-320 (selected paper)

- S. Miura, K. Ishida, K. Tanaka, E. Morita and M. Hashimoto
Integrasone Derivatives Isolated from Lepteutypa sp. KT4162 and Their Anti-HIV-1
Integrase Activity
J. Nat. Prod. 2023, 86(4), 1019-1024

- R. Kanehara, A. Tonouchi, K. Konno, H.i Koshino, M. Hashimoto,*
Isolation of cyclohumulanoids from Daedaleopsis tricolor and their biosynthesis based on in silico simulations
Tetrahedron, 2022, 92, 132251.

- Naoaki Kurisawa, Arihiro Iwasaki, Kazuya Teranuma, Shingo Dan, Chikashi
Toyoshima, Masaru Hashimoto, Kiyotake Suenaga
Structural Determination, Total Synthesis, and Biological Activity of Iezoside,
a Highly Potent Ca2+-ATPase Inhibitor from the Marine Cyanobacterium Leptochromothrix
valpauliae
J. Am. Chem. Soc. 2022, 144 (24), 11019–11032.
- Ayane Hayasaka, Kazuki Hashimoto, Katsuhiro Konno, Kazuaki Tanaka, Masaru Hashimoto
Isolation, Identification, and DFT-based Conformational Analysis of Sesquikarahanadienone and its Congeners from Freshwater Dothideomycetes Neohelicascus aquaticus KT4120
Bull. Chem. Soc. Jpn. 2022, 95 (5), 833-845
BCSJ Award article

- Takino, Junya, Kotani, Akari, Ozaki, Taro, Peng, Wenquan, Yu, Jie, Guo,
Yian, Mochizuki, Susumu, Akimitsu, Kazuya, Hashimoto, Masaru, Ye, Tao,
Minami, Atsushi, Oikawa, Hideaki
Biochemistry-Guided Prediction of the Absolute Configuration of Fungal
Reduced Polyketides
Angewandte Chemie International Edition, 2021, 60, 43, 23403-23411
- Ryuhi Kanehara, Akio Tonouchi, Katsuhiro Konno, and Masaru Hashimoto
Cyclohumulanoid Sesquiterpenes from the Culture Broth of the Basidiomycetous
Fungus Daedaleopsis tricolor
Molecules, 2021, 26 (14), 4364..

- Ayane Hayasaka, Kazuaki Tanaka, and Masaru Hashimoto
Isolation and Structural Elucidation of Novel Fusicoccan Dehydroxypericonicin
A from Roussoella sp.
Biosci. Biotech. Biochem. 2021, 85(8), 1798-1801.

-
Ryuhi Kanehara, Ayane Hayasaka, Kota Inose,
Takeshi Okamura, Satomi Miura, Kazuaki Tanaka, and Masaru Hashimoto
Decaspirones and Palmarumycins from Phaeoseptum sp. KT4106: Chirality Reinvestigation of Palmarumycins CP4a and CP5
Tetrahedron Lett., 2021, 92, 132251

-
Osamu Ishibashi, Mami Nishiyama, Eunsang
Kwon, Masaru Hashimoto, Shigefumi Kuwahara, Masaru Enomoto
Semipinacol rearrangement of a bicyclo [7.2. 0] undecane framework into
a bicyclo [6.3. 0] undecane skeleton: A model study on the biosynthesis
of seiridiasteriscane A
Biosci. Biotech. Biochem. 2021, 85(7), 1621-2627
-
Inose, Kota; Tanaka, Shizuya; Tanaka, Kazuaki; Hashimoto, Masaru,
Cyclohelminthol CPs: Scope and Limitations of Density-functional-theory-based Structural Elucidation of Natural Products
J. Org. Chem., 2021, 86( 2), 1505-1515..

- Wilanfranco C Tayone, Kotaro Ishida, Simon Goto, Janeth C Tayone, Masashi Arakawa, Eiji Morita, Masaru Hashimoto
Anti-Japanese Encephalitis Virus (JEV) Activity of Triterpenes and Flavonoids
from Euphorbia hirta
Philippine Journal of Science 149 (3), 603-613 2020
- M. Matsumoto, S. Miura, A. Tonouchi, Masaru Hashimoto*
DFT-Supported structure determination of gymunomitr-3(15)-en-4b,9b-diol
Tetrahedron, 2020, 76(27), 131301
- Wilanfranco C. Tayone, Mami Nishiyama, Kazuaki Tanaka Masaru Enomoto, and Masaru Hashimoto
DFT Supported Structural Elucidations of Seiridiasteriscane A, Unique 15-nor-Asteriscane
and Novel Pestalotiopsin Congeners from Seiridium sp. KT3957
Tetrahedron, 2020,76, (20), 131197

-
Mami Nishiyama, Wilanfranco C. Tayone, Hayato Maeda, Kazuaki Tanaka, Masaru
Hashimoto
DFT Supported Structural Revision of Seiricardines
Bull. Chem. Soc. Jpn. 2020, 93(6), 768-775.

-
Tetsuya Shiina, Taro Ozaki, Yusuke Matsu, Shota
Nagamine, Chengwei Liu, Masaru Hashimoto, Atsushi Minami, Hideaki Oikawa
Oxidative Ring Contraction by a Multifunctional Dioxygenase Generates the
Core Cycloocatadiene in the Biosynthesis of Fungal Dimeric Anhydride Zopfiellin
Org. Lett., 2020, 22 (5), 1997-2000.
- Uesugi S, Honmura Y, Nishiyama M, Kusakabe K, Tonouchi A, Yamashita T,
Hashimoto M, Kimura K-i.
Identification of neomacrophorins isolated from Trichoderma sp. 1212-03
as proteasome inhibitors.
Bioorg. Med. Chem. 2019, 27, 115161.
- Mami Nishiyama, Akio Tonouchi, Hayato Maeda, and Masaru Hashimoto
DFT calculation-assisted stereo-structural assignment of arundifungin
Chirality, 2020, 32, 17-31
- 橋本勝, 福士江里, Warren Hehre
DFT計算支援による天然物のNMR解析
日本核磁気共鳴学会機関誌、2019, vol10, 31-41.
- Hehre, W. J.; Kuunzinger, P.; Deppmeier, B.; Driessen, A.; Uchida, N.;
Hashimoto, M.; Fukushi, E.; Takata, Y.,
An Efficient Protocol for Accurately Calculating 13C Chemical Shifts of Conformationally Flexible Natural Products: Scope,
Assessment and Limitations.
J. Nat. Prod. 2019 82, 2299-2306.
.

- Kota Inose, Kazuaki Tanaka, Hiroyuki Koshino, Masaru Hashimoto
Cyclopericodiol and Novel Chlorinated Melleins Isolated from Periconia macrospinosa KT3863
Tetrahedron, 2019, 75, 130470

- Takahiro Ugai, Atsushi MInami, Shizuya Tanaka, Raro Ozaki, Chengwei Liu,
Hideyuki Shigemori, Masaru Hashimoto, Hideaki Oikawa
Biosynthetic machinery of 6‐hydroxymellein derivatives leading to cyclohelminthols
and palmaenones
ChemBioChem, accepted publication
- Mami Nishiyama, Hayato Maeda, Akio Tonouchi, and Masaru Hashimoto
Neomacrophorin and Premacrophorin Congeners from Trichoderma sp. 1212-03
Tetrahedron, 2019, 75, 2993-3000.

- Manami Matsumoto, Mami Nishiyama, Hayato Maeda, Akio Tonouchi, Katsuhiro Konno, Masaru Hashimoto
- Kota Inose, Kazuaki Tanaka, Takeshi Yamada, Hiroyuki Koshino, Masaru Hashimoto
- Yoshida, K.; Nagai, N.; Ichikawa, Y.; Goto, M.; Kazuma, K.; Oyama, K.-i.;
Koga, K.; Hashimoto, M.; Iuchi, S.; Takaya, Y.; Kondo, T.,
Structure of two purple pigments, catechiopyranocyanidins A and B from
the seed-coat of the small red bean, Vigna angularis
Scientific Reports 2019, 9, 1484.
- Shiina, T.; Nakagawa, K.; Fujisaki, Y.; Ozaki, T.; Liu, C.; Toyomasu, T.;
Hashimoto, M.; Koshino, H.; Minami, A.; Kawaide, H.; Oikawa, H.
Biosynthetic study of conidiation-inducing factor conidiogenone: heterologous
production and cyclization mechanism of a key bifunctional diterpene synthase.
Biosci. Biotech. Biochem. 2019, 83, 192-201.
- Maeno, M.; Sasaki, K.; Guo, M.; Hashimoto, M.; Shiro, M.; Shibata, N
Synthesis of Chiral Nonracemic α-Difluoromethylthio Compounds with Tetrasubstituted
Stereogenic Centers via a Palladium-Catalyzed Decarboxylative Asymmetric
Allylic Alkylation.
Org. Lett. 2018, 20, 7044-7048.
- 橋本勝
リンゴ果実におけるマイコパラサイト現象の生物有機化学
日本農薬学会誌, 2018, 43, 101-108.
- 橋本 勝
天然物構造決定におけるDFT計算の活用
有機合成化学協会誌 2018, 76, 842-850
- Shizuya Tanaka, Kazuaki Tanaka, Hayato Maeda, and Masaru Hashimoto
Cyclohelminthols Y1-Y4 Metabolites Possessing Two Spirocyclopropanes in their Structure
J. Org. Chem. 2018, 83, 5688-5697

- Manami Matsumoto, Shizuya Tanaka, Akio Tonouchi, and Masaru Hashimoto
12-Deoxyroridin J and 12-Deoxyepiisororidin E from Calcarisporium arbuscular
Tetrahedron Letters, 2018. 59, 1992-1995.

- Manami Matsumoto, Atsushi Ito, Akio Tonouchi, Masaaki Okazaki, Masaru Hashimoto
Stereochemical Correction and Total Structure of Roridin J
Tetrahedron, 2017, 73, 5430-5435.

- Shizuya Tanaka, Yuna Honmura, Shota Uesugi, Eri Fukushi, Kazuaki Tanaka,
Hayato Maeda, Ken-ichi Kimura, Tatsuo Nehira, Masaru Hashimoto
Cyclohelminthol X, a Hexa-substituted Spirocyclopropane from Helminthosporium velutinum yone96: Structural Elucidation, Electronic Circular Dichroism Analysis,
and Biological Properties
J. Org. Chem. 2017, 82, 5574-5582.

- Kazuaki Kusakabe, Yuna Honmura, Shota Uesugi, Akio Tonouchi, Hayato Maeda,
Ken-ichi Kimura, Hiroyuki Koshino, Masaru Hashimoto
Neomacrophorin X, a [4.4.3]Propellane-typed Meroterpenoid from Trichoderma sp. 1212-03
J. Nat. Prod. 2017, 80, 1484-1492.

- Atsushi Ito, Ikuya Kumagai, Miku Maruyama, Hayato Maeda, Akio Tonouchi,
Tatsuo Nehira, Ken-ichi Kimura, and Masaru Hashimoto
Homopetasinic acid isolated from Diaporthe sp. strain 1308-05
Tetrahedron Letters, 2016, 57, 1117-1119

- Yuna Honmura, Shota Uesugi, Hayato Maeda, Kazuaki Tanaka, Tatsuo Nehira,
Ken-ichi Kimura, Masaaki Okazaki, Masaru Hashimoto
Isolation, Absolute Structures, and Biological Properties of Cyclohelminthols I–IV from Helminthosporium velutinum yone96
Tetrahedron, 2016, 72, 1400-1405

- Miki Arayama, Shota Uesugi, Kazuaki Tanaka, Hayato Maeda, Tatsuo Nehira, Ken-ichi Kimura, Masaru Hashimoto
Homojesterones: vinylogous analogues of jesterone from Helminthosporium
velutinum TS28
Tetrahedron 2016, 72, 1031-1035.

- Miki Arayama, Hayato Maeda, Kazuaki Tanaka, Noboru Takada, Tatsuo Nehira, Masaru Hashimoto
"Achaetolide-II isolated from Helminthosporium velutinum TS28"
Tetrahedron, 2015, 71(41) 7900-7905

- Yuna Honmura, Hiroto Takekawa, Kazuaki Tanaka, Hayato Maeda, Tatsuo Nehira, Warren Hehre, and Masaru Hashimoto
Computation-Assisted Structural Elucidation of Epoxyroussoeone and Epoxyroussoedione
Isolated from Roussoella japanensis KT1651
J. Nat. Prod., 2015, 78 (7), 1505–1510
- Miki Arayama, Tatsuo Nehira, Hayato Maeda, Kazuaki Tanaka, Hisashi Miyagawa, Tamio Ueno, Seijiro Hosokawa, Masaru Hashimoto
Isolation, ECD Assisted Structural Analyses, Biosynthetic Discussions,
and Biological activities of epi-Cochlioquinones D and its Derivatives
Tetrahedron, 2015, 71, 4788-4794.

- 橋本勝
リンゴ果実上におけるマイコパラサイト現象の分子機構
有機合成化学協会誌, 73 230-240 (2015)
- Ito, A.; Maeda, H.; Tonouchi, A.; Hashimoto, M.
Relative and absolute structure of phomolide C
Biosci. Biotech. Biochem. 2015, 79(7) 1067-1069.

- Fujii, M.; Chiba, H.; Tamayama, N.; Kanamaru, S.; Hashimoto, M.
Isotopic Differentiation Protocol, a Selective Extraction of C- and N-Terminal
Ions in ESI-Ms/Ms De Novo Peptide Sequencing
Nat. Prod. Chem. Res. 2015, 3, 164.

- Hirose, A.; Kudo, S.; Murakami, T.; Tanaka, K.; Harada, K.; Hashimoto,
M.
"Lambertellin System, the mechanism for fungal replacement of Moniliniafructigena with Lambertellacorni-maris without competitive inhibition on ager media."
Bioorg. Med. Chem., 22, 2489, (2014).

- 橋本勝
「リンゴ果実におけるマイコパラサイト現象の生物有機化学的研究」
日本化学会生体機能関連部会ニュースレター、Vol. 28, No.3 (2014. 1. 23)
- Hirose, A.; Maeda, H.; Tonouchi, A.; Nehira, T.; Hashimoto, M.
Neomacrophorin I, II, and III, novel drimenyl cyclohexanes with hydroxylated
butanoates from Trichoderma sp. 1212-03
Tetrahedron, 70, 1458-1463 (2014).

- Tayone, W. C.; Tayone, J. C.; Hashimoto, M
Isolation and structure elucidation of potential anti-dengue metabolites from tawa-tawa (Euphorbia hirta Linn.)
Walailak Journal of Science and Technology , 2014, 11, 825-832..
- 橋本勝
「PlipastatinとFengucinにおける構造混乱の終結」
化学と生物、51, 840-843 (2013).
- Yasumura, R.; Ashtekar, K. D.; Tonouchi, A.; Nehira, T.; Borhan, B.; Hashimoto,
M.
7-β- and 10-β-Hydroxylated congeners of CAF-603; elucidation of absolute
configuration of CAF-603 family, and their SAR studies in the anti-fungal
activity
Tetrahedon 2013, 69, 9469-9474 (2013).
- 橋本勝
Spartanの化学シフト計算による天然物の構造決定
Wavefunction User Letter No4.(右クリックで保存してから開くことができます。)
- Takekawa, H.; Tanaka, K.; Fukushi, E.; Nehira, T.; Hashimoto, M.
Roussoellols A and B, Tetracyclic Fusicoccanes from Roussoella hysterioides
J. Nat. Prod., 76, 1047–1051 (2013).

- Takada, N.; Wakita, E.; Yamazaki, E.; Hashimoto, M.; Koda, Y. T
Methyl 3-iso-cucurbate, a potential bolting inhibitor to Brassica rapa
Tetrahedron 69, 5426–5430, (2013).
- R. Yasumura; K. Tanaka.; T. Nehira; M. Hashimoto.
Structural corrections of photinides A, B and their novel derivatives
Tetrahedron, 68, 7991-7996 (2012).

- M. Honma, K. Tanaka, K. Konno, K. Tsuge, T. Okuno, M. Hashimoto
Termination of the structural confusion between plipastatin A1 and fengycin
IX
Bioorg. Med. Chem., 20, 3793-3798 (2012).

- S. Kanamaru, M. Honma, T. Murakami, T. Tsushima, S. Kudo, K. Tanaka, K.
Nihei, T. Nehira, M. Hashimoto,
"Absolute Stereochemistry of Altersolanol A and Alterporriols"
Chirality, 24, 137–146 (2012).

- K. Yamamoto, K. Yoon, K. Ueda, M. Hashimoto, J. R. Sparrow,
"A novel bisretinoid of retina is an Adduct on Glycerophosphoetanolamine"
Investigative Ophthalmology & Visual Science, 51, 9084-9090 (2011).
- W. C. Tayone, S. Kanamaru, M. Honma, K. Tanaka, T. Nehira, M. Hashimoto
"Absolute Stereochemistry of Novel Isochromanone Derivatives from Leptosphaeria sp. KTC 727"
Biosci. Biotech. Biochem, 75, 2390-2393 (2011).
- S. Noguchi, S. Takemoto, S. Kidokoro, K.. Yamamoto, M. Hashimoto
"Syntheses of cellotriose and cellotetraose analogues as transition state
mimics for mechanistic studies of cellulases"
Bioorg. Med. Chem, 19, 3812–3830 (2011).

- N. Akiyama, S. Noguchi, M. Hashimoto
"Stereochemical differentiation in the Simmons-Smith reaction for
cyclopropanated glucopyranose derivatives as molecular probes for glycosidases"
Biosci. Biotech. Biochem, 2011, 75, 1380-1382.
-
Zaharenko, A.; Picolo, G.; Ferreira, W.; Murakami, T.; Kazuma, K.; Hashimoto, M.; Cury, Y.; de Freitas, J.; Konno, K
"Bunodosine 391: a new analgesic acylamino acid from the venom of the sea
anemone Bunodosoma cangicum"
J. Nat. Products, 74, 378–382 (2011).

-
Wilanfranco T. C.; Honma, M.; Kanamaru S.; Noguchi, S.; Tanaka, K.; Nehira,
T.; Hashimoto, M..
"Stereochemical investigations of isochromenone and isobenzofuranone isolated
from Leptosphaeria sp. KTC 727"
J. Nat. Products, 74, 425–429 (2011).

- Yamamoto, K.; Noguchi, S.; Takada, N.; Miyairi, K.; Hashimoto, M.
"Synthesis of a trigalacturonic acid analogue mimicking the expected
transition state in the glycosidases"
Crabohydr. Res. 345, 572-585, (2010).

- Honma, M.; Kudo, S.; Takada, N.; Miura, T.; Hashimoto, M.
"Novel Neofusapyrones Isolated from Verticillium dahliae as Potent Antifungal Substances"
Bioorg. Med. Chem. Lett., 20, 709-712 (2010).

-
Wilanfranco T. C.; Shindo, S.; Murakami, T.; Hashimoto, M.; Tanaka, K.; Takada, N.
"Absolute stereochemistry and conformational analysis of achaetolide isolated
from Ophiobolus sp."
Tetrahedron, 65, 7464-7467 (2009).

- T. Murakami, N. Takada, M. Hashimoto
"Biosynthetic studies of spiroleptosphol"
Bioorg. Med. Chem. Lett., 19, 1122-1125 (2009).

- T. Murakami, T. Tsushima, N. Takada, K. Tanaka, K. Nihei, T. Miura, M.
Hashimoto
"Four Analogues of Spiroleptosphol isolated from Leptosphaeria doliolum"
Bioorg. Med. Chem. 19, 492-495 (2009).

- Kudo, S., Murakami, T., Miyanishi, J., Tanaka, K., Takada, N., Hashimoto,
M.
"Isolation and absolute stereochemistry of optically active sydonic acid
from from Glonium sp. (Hysteriales, Ascomycota)"
Biosci. Biotech. Biochem, 73, 203-204 (2009).
- Murakami, T.; Takada, N.; Hehre, W.; Hashimoto, M.,
Structure and Biosynthesis of Norneolambertellin Produced by Lambertella sp.1346.
Bioorg. Med. Chem, Lett, 18, 16, 4547-4549 (2008).

- 橋本勝
"Spartan Essentialを導入して ~演習講義「コンピュータ分子設計学」への展開~"
日本化学会情報化学部会誌 26, 106-112 (2008)
- Hashimoto, M.; Tsushima, T.; Murakami, T.; Nomiya, M.; Takada, N.; Tanaka,
K.
"Spiroleptosphol isolated from Leptosphaeria doliolum"
Bioorg. Med. Chem, Lett, 18, 14, 4228-4231 (2008).

- Nomiya, M., Murakami, T., Takada, N., Okuno, T., Harada, Y., Hashimoto,
M.
"Syntheses of Lambertellols and Their Stable Analogues; Investigation of
the Real Active Species in the Mycoparasitism by Lambertella Speciese"
J. Org. Chem, 73, 5039-5047 (2008.)

- Yamamoto, K., Sato, Y., Ishimori, A., Miyairi, K., Okuno, T., Nemoto, N.,
Shimizu, H., Kidokoro, S., Hashimoto, M.
"Synthesis of D-trigalacturonic acid methylglycoside"
Biosci. Biotech. Biochem, 71, 1230-1235 (2008)
- Schuetz, A.; Murakami, T.; Takada, N.; Junker, J.; Hashimoto, M.; Griesinger,
C
"Rdc-enhanced NMR spectroscopy in structure elucidation of natural products/small molecules: Sucro-neolambertellin as a testcase"
Angew. Chem. Int. Ed. 47, 2032-2034 (2008).

- T. Murakami, N. Takada, Y. Harada, T. Okuno, M. Hashimoto,
"Stimulation of the Biosynthesis of the Antibiotics Lambertellols by the
Mycoparasitic Fungus Lambertella corni-maris under the Acidic Conditions Produced by Its Host Fungus in Vitro",
Biosci. Biotech. Biochem., 71, 1230-1235 (2007)
- Hashimoto, M., Murakami, T., Funahashi, K., Tokunaga, T., Nihei, K., Okuno,
T., Kimura, T., Naoki, H., Himeno, H.
An RNA polymerase inhibitor, cyclothiazomycin B1, and its isomer.
Bioorg. Med. Chem,, 14, 8259–8270 (2006)

- 橋本勝
ピラノース環酸素を硫黄原子で置換したチオオリゴサッカリドの合成研究, (総合論文)
有機合成化学協会誌, 64(7), 766-777, (2006).
- Yamamoto, K., Watanabe, N., Matsuda, H., Oohara, K., Araya, T., Hashimoto,
M., Miyairi, K., Okazaki, I., Saito, M., Shimizu, T., Kato, H., Okuno,
T.
Design, synthesis, and enzymatic property of a sulfur-substituted analogueof trigalacturonic acid
Bioorg. Med. Chem, Lett., 15, 22, 4932-4935 (2005).

- Murakami, T., Hashimoto, M., Okuno, T.
Isolation, structure elucidation, preparation,and biological properties
of neolambertellin
Bioorg. Med. Chem, Lett., 15, 4185-4188 (2005)

- Morii, Y., Matsuda, Y., Ohara, K., Hashimoto, M., Miyairi, K., Okuno, T.
Synthetic studies on oligosaccharides composed of 5-thioglucopyranose units
Bioorg. Med. Chem., 13, 5113-5144 (2005)

- Murakami T., Sasaki A.., Fukushi E., Kawabata J., Hashimoto M., Okuno T.
Lambertellol C, a labile and novel biosynthetic congener of lambertellols
A and B
Bioorg. Med. Chem. Lett., 15, 2587-2590 (2005).

- Murakami T., Sasaki A., Fukushi E., Kawabata J., Hashimoto M., Okuno T.
Optimization of isotope-labeling conditions for lambertellin based on isotope patterns observed by mass spectrometry
Bioorg. Med. Chem. Lett., 15, 2591-2594 (2005).
- Nihei K., YING B.-P., Murakami T., Matsuda H., Hashimoto M. & Kubo
I.
Pachyelasides A-D, Novel Molluscicidal Triterpene Saponins from
Pachyelasma Tessmannii
J. Agric. Food Chem., 53, 608-613
(2005).
- Murakami T., Takahashi Y., Fukushi E., Kawabata J., Hashimoto M., Okuno
T.& Harada Y.
Biosynthesis of Lambertellols Based on the High Specific Incorporation
of the 13C-Labeled Acetates and Their Biological Properties,
J, Am. Chem. Soc., 126, 9214-9220 (2004).

- Fujita J., Matsuda H., Yamamoto K., Morii Y., Hashimoto M., Okuno
T.& Hashimoto K.
Synthesis of thiosaccharides employing the Pummerer
rearrangement of tetrahydrothiopyran oxides,
Tetrahedron, 60,
6829-6851 (2004).

- Murakami, T., Morikawa, Y., Hashimoto, M., Okuno, T. & Harada, Y.
Lambertellols A and B, Novel 3,4-Dihydronaphthalen-1(2H)-ones with Spiro-butenolide Produced by Lambertella sp.1346.
Org. Lett.
6, 157-160 (2004).
- Matsuda, H., Fujita, J., Morii, Y., Hashimoto, M., Okuno, T. &
Hashimoto, K.
Pummerer rearrangement of 1-deoxy-5-thioglucopyranose oxides;
novel synthesis of 5-thioglucopyranose derivatives.
Tetrahedron
Lett., 44, 4089-4093 (2003).
- Matsuda, H., Ohara, K., Morii, Y., Hashimoto, M., Miyairi, K. & Okuno,
T.
α-Selective Glycosylation with 5-thioglucopyranosyl Donnors; Synthesis
of an Isomaltotetraoside mimic Composed of 5-thioglucopyranose Units.
Bioorg. Med. Chem. Lett., 13, 1063-1066 (2003).
- Hashimoto, M., Matsumoto, M., Yamada, K. & Terashima,
S. Synthetic
studies of carzinophilin. Part 4: Chemical and biological properties of
carzinophilin analogues.
Tetrahedron 59, 3089-3097
(2003).
- Hashimoto, M., Sugiura, M. & Terashima, S.
Synthetic studies of
carzinophilin. Part 3: Synthetic approach toward carzinophilin and successful
synthesis of 13-O-desacetyl-12,13-di-O-benzyl-4-O-methylcarzinophilin.
Tetrahedron 59, 3063-3087 (2003).
- Hashimoto, M., Matsumoto, M. & Terashima, S.
Synthetic studies of
carzinophilin. Part 2: Synthesis of
3,4-dibenzyloxy-2-methylidene-1-azabicyclo[3.1.0]hexane systems corresponding to
the C1-17 fragment of carzinophilin.
Tetrahedron 59, 3041-3062
(2003).
- Hashimoto, M., Matsumoto, M. & Terashima, S.
Synthetic studies of
carzinophilin. Part 1: Synthesis of 2-methylidene-1-azabicyclo[3.1.0]hexane
systems related to carzinophilin.
Tetrahedron 59, 3019-3040
(2003).
- Ohara, K., Matsuda, H., Hashimoto, M., Miyairi, K. & Okuno,
T
β-Selective Glycosylation of 5-Thioglucopyranose Derivatives: Synthesis
of β-(1-6)Linked 5'-Thioglucopyranosyl Disaccharides.
Chemistry Lett.
2002, 626-627 (2002).
- Matsuda, H., Hashimoto, M. & Okuno, T.
Novel Preparation of
(2-Azidomethyl)benzoic Acid and an Application as a Protective Group.
Syn. Commun. 32, 3347-355 (2002).
- Aoki, K., Takahashi, M., Hashimoto, M., Okuno, T., Kurata, K. & Suzuki,
M.
Total Synthesis of Both Enantiomers of Dictyochromenol and their
(Z)-Isomers.
Biosci. Biotech. Biochem. 66, 1915-1924
(2002).
- Ben-Shabat, S., Craig, P., A, Hashimoto, M., Liu, J., Koji, N. &
Sparrow, J.
Fluorescent Pigments if the Retinal Pigment Epithelium and
Age-related Macular Degeneration.
Bioorg. Med. Chem. Lett. 11,
1533-1540 (2001).
- Lin, S., Fang, K., Hashimoto, M., Nakanishi, K. & Ojima, I..
Design and Synthesis of a novel Photoaffinity Taxoid as a Potential Probe
for the Study of Paclitaxel-microtubules Interactions.
Tetrahedron Lett., 41,
4287-4290 (2000).
- Sparrow, J., Craig, P., A, Hashimoto, M. & Nakanishi, K.
A2E, a Lipofuscin Fluorophore, in Human Retinal Pigmented Epithelial Cells
in Culture.
IVOS 40, 2988-2995 (1999).
- Lou, J., Hashimoto, M., Nina, B. & Nakanishi, K.
Enantioselective
Binding of an 11-cis-Locked Cyclopropyl Retinal. The Conformation of Retinal in
Bovine Rhodopsin.
Org. Lett. 1, 51-54 (1999).
- Hashimoto, M. & Fujimoto, Y.
One Step and Convenient Preparations of
4-Hydroxyretinal and 4-Oxoretinal.
Syn. Commun. 29, 3793-3797
(1999).
- Hashimoto, M., Liu, Y., Fang, K., Li, H.-y. & Nakanishi,
K.
Preparation and Biological Properties of Biotinylated PhTX Derivatives.
Bioorg. Med. Chem. 7, 1181-1194 (1999).
- Hashimoto, M. & Terashima, S.
A Stereoselective Synthesis of
4-O-methyl-13-Desacetyl-12,13-di-O-benzylcarzinophilin.
Heterocycles
47, 59-64 (1998).
- Fang, K., Hashimoto, M., Jockusch, S., Turro, N. J. & Nakanishi, K.
A Bifunctional Photoaffinity Probe for Ligand/Receptor Interaction Studies.
J,
Am. Chem. Soc., 120, 8543–8544 (1998).
- Craig, P., A, Hashimoto, M., Nakanishi, K., Dillon, J. & Sparrow,
J.
Isolation and One-step Preparation of A2E and Iso-A2E, Fluorophores from
Human Retinal Epithelium.
Proc. Nat. Acd. Sci. USA, 95,
14609-14613 (1998).
- Yoshino, T., Nagata, Y., Itoh, E., Hashimoto, M., Katoh, T. & Terashima,
S.
Total Synthesis of an Enantiomeric Pair of Fr900482. 2. Synthesis of the
Aromatic and Optically Active Aliphatic Segments.
Tetrahedron 53,
10239-10252 (1997).
- Yoshino, T., Nagata, Y., Itoh, E., Hashimoto, M., Katoh, T. & Terashima,
S.
Total Synthesis of Natural (+)-FR-900482. 2. Efficient Synthesis of the Aromatic and Optically Active Aliphatic Fragments.
Tetrahedron Lett.,
37, 3475-3478 (1996).
- Nakajima, N., Kirihara, M., Matsumoto, M., Hashimoto, M., Katoh, T. &
Terashima, S.
One-step Synthesis of (5)-Epi-Hydantocidin.
Heterocycles 42, 503-508 (1996).
- Nakajima, N., Matsumoto, M., Kirihara, M., Hashimoto, M., Katoh, T. &
Terashima, S.
Novel Synthesis of (+)-Hydantocidin Based on the Plausible
Biosynthetic Pathway.
Tetrahedron 52, 1177-1194 (1996).
- Tamura, O., Hashimoto, M., Kobayashi, Y., Katoh, T., Nakatani, K., Kamada,
M., Hayakawa, I., Akiba, T. & Terashima, S.
Synthetic Studies on the Key
Component of the New Generation of Quinolonecarboxylic Acid, DU-6859. 2.
Asymmetric Synthesis of (1R,2S)-2-Fluorocyclopropylamine.
Tetrahedron
50, 3905-3194 (1994).
- Tamura, O., Hashimoto, M., Kobayashi, Y., Katoh, T., Nakatani, K., Kamada,
M., Hayakawa, I., Akiba, T. & Terashima, S.
Synthetic Studies on the Key
Component of the New Generation of Quinolonecarboxylic Acid, DU-6859. 1.
Synthesis of (1R,2S)-2-Fluorocyclopropylamine by the Use of Optical Resolution.
Tetrahedron 50, 3889-3904 (1994).
- Hashimoto, M. & Terashima, S.
A Novel Synthesis of the C1-C17
Fragment of Carzinophilin.
Tetrahedron Lett., 35, 9409-9412
(1994).
- Hashimoto, M. & Terashima, S.
A Stereoselective Synthesis of a Novel
Model Compound of Carzinophilin Carrying the C6-C13 Unit with Correct
Stereochemistry.
Chemistry Lett., 1101-1104 (1994).
- Hashimoto, M., Matsumoto, M., Yamada, K. & Terashima, S.
Synthesis,
Chemical Reactivity, and Cytotoxicity of Carzinophilin Congeners Carrying a
2-(Acylamino-1-alkoxycarbonyl)methylidene-1-azabicyclo[3.1.0]hexane System.
Tetrahedron Lett., 35, 2207-2210 (1994).
- Tamura, O., Hashimoto, M., Kobayashi, Y., Katoh, T., Nakatani, K., Kamada,
M., Hayakawa, I., Akiba, T. & Terashima, S.
Asymmetric Synthesis of
(1R,2S)-2-Fluorocyclopropylamine. the Key Intermediate of the New Generation of
quinolonecarboxylic acid, DU-6859.
Tetrahedron Lett., 33,
3487-3490 (1992).
- Tamura, O., Hashimoto, M., Kobayashi, Y., Katoh, T., Nakatani, K., Kamada,
M., Hayakawa, I., Akiba, T. & Terashima, S.
Synthesis and Optical
Resolution of dl-cis-2-Fluorocyclopropylamine, the Key Component of the New
Generation of Quinolonecarboxylic acid, DU-6859.
Tetrahedron Lett.,
34, 3483-3486 (1992).
- Hashimoto, M., Yamada, K. & Terashima, S.
Chemical Reactivity, and
Cytotoxicity of 2-Bis(alkoxycarbonyl)methylidene-1-azabicyclo[3.1.0]hexane
Systems Related to Antitumor Antibiotic Carzinophilin A.
Chemistry Lett.,
975-978 (1992).
- Hashimoto, M., Harigaya, H., Yanagiya, M. & Shirahama, H.
Total
Synthesis of the meso-Triterpene Polyether Teurilene.
J. Org. Chem.
56, 2299-2311 (1991).
- Hashimoto, M., Kan, T., Nozaki, K., Yanagiya, M., Shirahama, H. &
Matsumoto, T.
Total Synthesis of (+)-Thyrsiferol, (+)-Thyrsiferyl 23-Acetate,
and Teurilene.
J. Org. Chem. 55, 5088-5017 (1990).
- Hashimoto, M., Yanagiya, M., Okuno, T. & Shirahama, H.
The Absolute
Configuration of 4,6-decadiyne-1,3,8-triol Isolated from Gymnopiliun
spectabilis.
Bull. Chem. Soc. Jpn. 62, 2751-2752 (1989).
- Kan, T., Hashimoto, M., Yanagiya, M. & Shirahama, H.
Effective
Deprotection of 2-(Trimethylsilylethoxy)methylated Alcohols (SEM Ethers).
Synthesis of Thyrsiferyl-23 Acetate.
Tetrahedron Lett., 29,
5417-5418 (1988).
- Hashimoto, M., Harigaya, H., Yanagiya, M. & Shirahama, H.
A Short
Step Synthesis of Teurilene. Stereocontrolled Sequential Double Cyclization of
the C30-Tetraenetetraol to the Tandem Tetrahydrofurane System.
Tetrahedron
Lett., 29, 5947-5948 (1988).
- Hashimoto, M., Yanagiya, M. & Shirahama, H.
Total Synthesis of
meso-Triterpene Ether, Teurilene. Chemistry Lett., 645-646 (1988).
- Hashimoto, M., Kan, T., Nozaki, K., Yanagiya, M., Shirahama, H. &
Matsumoto, T.
Total Synthesis of (+)-Thyrsiferol and (+)-Venustatriol.
Tetrahedron Lett., 29, 1143-1144 (1988).
- Hashimoto, M., Kan, T., Yanagiya, M., Shirahama, H. & Matsumoto,
T.
Synthesis of A-B-C-ring Segment of Thyrsiferol: Construction of a Strained
Tetrahydropyrane Ring Existing as a Boat Form.
Tetrahedron Lett.,
28, 5665-5668 (1987).